{"id":16498,"date":"2020-11-30T15:47:25","date_gmt":"2020-11-30T15:47:25","guid":{"rendered":"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/"},"modified":"2022-09-28T12:16:58","modified_gmt":"2022-09-28T12:16:58","slug":"23985","status":"publish","type":"cpt_aktualne_spravy","link":"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/","title":{"rendered":"Pomenovanie nov\u00fdch p\u00f3rovit\u00fdch materi\u00e1lov nesie n\u00e1zov UPJ\u0160"},"content":{"rendered":"

Zl\u00fa\u010deniny typu metal-organic frameworks skr\u00e1tene MOFs \u00a0patria do triedy hybridn\u00fdch p\u00f3rovit\u00fdch materi\u00e1lov obsahuj\u00facich anorganick\u00fa (kovov\u00e9 centrum) a\u00a0organick\u00fa (most\u00edkuj\u00faci ligand) zlo\u017eku, ktor\u00e9 s\u00fa navz\u00e1jom spojen\u00e9 prostredn\u00edctvom koordina\u010dnej v\u00e4zby do trojrozmern\u00fdch polym\u00e9rnych siet\u00ed. V\u010faka pr\u00edtomnosti p\u00f3rov r\u00f4znych tvarov a\u00a0ve\u013ekost\u00ed nach\u00e1dzaj\u00fa MOFs uplatnenie v\u00a0r\u00f4znorod\u00fdch oblastiach ako adsorpcia a\u00a0delenie plynov, katal\u00fdza, nosi\u010de lie\u010div, i\u00f3nomeni\u010de, senzorika a\u00a0mnoh\u00e9 \u010fal\u0161ie. \u00a0<\/p>\n

Ich presn\u00e9 chemick\u00e9 zlo\u017eenie je \u010dasto zlo\u017eit\u00e9 a predov\u0161etk\u00fdm dlh\u00e9. Z tohto d\u00f4vodu sa v pr\u00edpade ich ozna\u010dovania pou\u017e\u00edvaj\u00fa 3-4 p\u00edsmenov\u00e9 skratky + poradov\u00e9 \u010d\u00edslo (napr. MIL-101). V\u00fdskumn\u00e9 pracovisk\u00e1 v\u00e4\u010d\u0161inou pou\u017e\u00edvaj\u00fa skratku univerzity na ktorej boli tieto materi\u00e1ly pripraven\u00e9, ako napr\u00edklad:<\/p>\n

– MIL (Material Institute of Lavoisier, Versailles, Franc\u00fazsko),<\/p>\n

– NOTT (Nottingham University, Nottingham, Ve\u013ek\u00e1 Brit\u00e1nia),<\/p>\n

– DUT (Dresden University of Technology, Dr\u00e1\u017e\u010fany, Nemecko),<\/p>\n

– UiO (University of Oslo, Oslo, N\u00f3rsko),<\/p>\n

– SNU (Seoul National University, Soul, Ju\u017en\u00e1 K\u00f3rea) a\u00a0in\u00e9.<\/p>\n

Na Katedre anorganickej ch\u00e9mie \u00dastavu chemick\u00fdch vied PF UPJ\u0160 sa realizuje \u00a0dlhoro\u010dn\u00fd v\u00fdskum p\u00f3rovit\u00fdch materi\u00e1lov typu metal-organic frameworks. Tento rok, v\u00fdsledky svojej pr\u00e1ce RNDr. Miroslav Alm\u00e1\u0161i, PhD. a\u00a0kolekt\u00edv<\/strong> publikovali v\u00a0prest\u00ed\u017enom britskom \u010dasopise RSC Advances<\/strong>, ktor\u00fd je pod z\u00e1\u0161titou Britskej kr\u00e1\u013eovskej chemickej spolo\u010dnosti (RSC \u2013 The Royal Society of Chemistry). V\u00a0\u0161t\u00fadii<\/strong><\/a> s\u00fa op\u00edsan\u00e9 a\u00a0charakterizovan\u00e9 \u0161tyri nov\u00e9 MOF zl\u00fa\u010deniny<\/strong> obsahuj\u00face v\u00e1penat\u00e9, strontnat\u00e9 a\u00a0b\u00e1rnat\u00e9 kati\u00f3ny, ktor\u00e9 boli testovan\u00e9 ako adsorbenty plynov pri r\u00f4znych podmienkach, pri\u010dom materi\u00e1ly vykazuj\u00fa zv\u00fd\u0161en\u00fa afinitu k\u00a0molekul\u00e1m vod\u00edka. V\u00a0\u010dl\u00e1nku bola po prv\u00fdkr\u00e1t zadefinovan\u00e1 a\u00a0pou\u017eit\u00e1 skratka UPJS<\/strong> na ozna\u010dovanie p\u00f3rovit\u00fdch materi\u00e1lov typu MOF pripraven\u00fdch na Katedre anorganickej ch\u00e9mie. Aj tak\u00fdmto sp\u00f4sobom chceme da\u0165 do povedomia a prezentova\u0165 Univerzitu Pavla Jozefa \u0160af\u00e1rika v\u00a0Ko\u0161iciach v\u00a0celosvetovom meradle.<\/p>\n

Odkaz na publikovan\u00fa \u0161t\u00fadiu:<\/strong><\/p>\n

Alm\u00e1\u0161i, M., Zele\u0148\u00e1k, V., Gyepes, R., Zau\u0161ka, \u013d., Bourrelly, S. (2020). A series of four novel alkaline earth metal-organic frameworks constructed of Ca(ii), Sr(ii), Ba(ii) ions and tetrahedral MTB linker: structural diversity, stability study and low\/high-pressure gas adsorption properties. RSC Advances<\/em>, 10 (54), pp. 32323-32334.<\/p>\n

Viac<\/a><\/p>\n

\"\"<\/p>\n

Pripraven\u00e9 zl\u00fa\u010deniny typu MOF s\u00a0chemick\u00fdm zlo\u017een\u00edm, skratkou UPJS a\u00a0pr\u00edslu\u0161n\u00fdm poradov\u00fdm \u010d\u00edslom a\u00a0v\u00fdsledky adsorp\u010dn\u00fdch meran\u00ed.<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

Na Katedre anorganickej ch\u00e9mie \u00dastavu chemick\u00fdch vied\u00a0 PF UPJ\u0160 sa realizuje \u00a0dlhoro\u010dn\u00fd v\u00fdskum p\u00f3rovit\u00fdch materi\u00e1lov typu metal-organic frameworks. Tento rok, v\u00fdsledky svojej pr\u00e1ce RNDr. Miroslav Alm\u00e1\u0161i, PhD. a\u00a0kolekt\u00edv<\/strong><\/span> publikovali v\u00a0prest\u00ed\u017enom britskom \u010dasopise RSC Advances, ktor\u00fd je pod z\u00e1\u0161titou Britskej kr\u00e1\u013eovskej chemickej spolo\u010dnosti….<\/p>\n","protected":false},"author":1,"featured_media":16499,"menu_order":0,"template":"","meta":{"_acf_changed":false,"_editorskit_title_hidden":false,"_editorskit_reading_time":0,"_editorskit_is_block_options_detached":false,"_editorskit_block_options_position":"{}"},"categories":[],"tags":[],"tax_aktuality":[],"class_list":["post-16498","cpt_aktualne_spravy","type-cpt_aktualne_spravy","status-publish","has-post-thumbnail","hentry"],"acf":{"acf_link_na_externy_obsah":""},"yoast_head":"\nPomenovanie nov\u00fdch p\u00f3rovit\u00fdch materi\u00e1lov nesie n\u00e1zov UPJ\u0160 - Pr\u00edrodovedeck\u00e1 fakulta | UPJ\u0160<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/\" \/>\n<meta property=\"og:locale\" content=\"sk_SK\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Pomenovanie nov\u00fdch p\u00f3rovit\u00fdch materi\u00e1lov nesie n\u00e1zov UPJ\u0160 - Pr\u00edrodovedeck\u00e1 fakulta | UPJ\u0160\" \/>\n<meta property=\"og:description\" content=\"Na Katedre anorganickej ch\u00e9mie \u00dastavu chemick\u00fdch vied\u00a0 PF UPJ\u0160 sa realizuje \u00a0dlhoro\u010dn\u00fd v\u00fdskum p\u00f3rovit\u00fdch materi\u00e1lov typu metal-organic frameworks. Tento rok, v\u00fdsledky svojej pr\u00e1ce RNDr. Miroslav Alm\u00e1\u0161i, PhD. a\u00a0kolekt\u00edv publikovali v\u00a0prest\u00ed\u017enom britskom \u010dasopise RSC Advances, ktor\u00fd je pod z\u00e1\u0161titou Britskej kr\u00e1\u013eovskej chemickej spolo\u010dnosti....\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/\" \/>\n<meta property=\"og:site_name\" content=\"Pr\u00edrodovedeck\u00e1 fakulta | UPJ\u0160\" \/>\n<meta property=\"article:modified_time\" content=\"2022-09-28T12:16:58+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/www.upjs.sk\/app\/uploads\/sites\/10\/2022\/09\/akt_veda_30112020.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"597\" \/>\n\t<meta property=\"og:image:height\" content=\"326\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Predpokladan\u00fd \u010das \u010d\u00edtania\" \/>\n\t<meta name=\"twitter:data1\" content=\"2 min\u00faty\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/\",\"url\":\"https:\/\/www.upjs.sk\/prirodovedecka-fakulta\/actual-news\/23985\/\",\"name\":\"Pomenovanie nov\u00fdch p\u00f3rovit\u00fdch materi\u00e1lov nesie n\u00e1zov UPJ\u0160 - 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